A novel report on Eosin Y functionalized MWCNT as an initiator for ring opening polymerization of ɛ-caprolactone

This research conducted ring opening polymerization (ROP) of ?-caprolactone (C.L.) with a novel initiator, namely; Eosin Y functionalized multiwalled carbon nanotube (MWCNT) at 140 °C with nitrogen sparge under different concentrations. ROP of C.L. carried out at two different experimental conditions similar to variations in [M₀/I₀] and [C.L.]. Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy confirmed the structure of MWCNT-Eosin Y initiated ROP of C.L. Gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), UV–visible spectroscopy (UV–vis), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) further characterized the structure. UV–visible spectroscopy determined the binding constant (K), for samples prepared under different [C.L.].     

物相定量分析在铝工业中的应用

总结介绍了到目前为止在铝工业中应用的物相定量分析方法,分析了各种方法的应用范围以及优缺点,包括化学物相定量法、外标法、化学物相计算法、X射线衍射增量法、K值法、绝热法、Rietveld全谱拟合定量法、K值法和化学物相计算法结合以及Zevin无标定量法等.结果表明:每种物相定量分析方法都有各自的优点和缺点,需要根据样品的...     

Influence of cyclic frequency on oxidation behavior of K38 superalloy with yttrium additions at 1 273 K

Cyclic oxidation test is a fundamental method to assess lifetime of materials in high temperature environment.Cycle length or cyclic frequency is one important variable in cyclic oxidation testing.In present work,cyclic oxidation tests were performed on cast K38 alloys with 0 wt.%,0.1 wt.%,and 0.5 wt.% yttrium additions at 1 273 K respectively.Two cyclic frequencies were used to investigate the influence of cycle length (1 h vs.20 h) on the high temperature oxidation behavior of superalloy.The results showe...     

MAGNOLOL ENTRAPPED ULTRA-FINE FIBROUS MATS ELECTROSPUN FROM POLY(ETHYLENE GLYCOL)-b-POLY(L-LACTIDE) AND IN VITRO RELEASE

Ultra-fine fibrous mats with magnolol entrapped have been prepared by eleetrospinning biodegradable copolymer poly(ethylene glycol) blocked poly(L-lactide). Drug entrapment was perfect which was confirmed by scanning electron microscopy and differential scanning calorimetry. According to in vitro drug release investigation by high performance liquid chromatography, it was found that fibers with 10%, 20% and 30% drug entrapped respect to polymer (mass ratio) presented dramatically different drug release behavior and degradation behavior under the effect of proteinase K. The reason 2 be that fibers with 10% drug entrapped was more easily affected by enzyme while, to some degree, magnolol in fibers with 20% and 30% entrapped prevented polymer from being degraded by enzyme.     

Chemical speciation of chlorine in particulate matter by wavelength-dispersive PIXE technique

Chemical speciation of chlorine (Cl) in atmospheric particulate matter (APM) was performed by using a wavelength-dispersive PIXE spectrograph based on high-resolution measurement of Cl-Kβ emission. Samples of atmospheric particles were size-fractioned and collected by a cascade impactor at an urban area in Tokyo. The target position with respect to the spectrograph was precisely adjusted by a 2D laser displacement sensor to achieve high detection efficiency. The samples were irradiated with 2 MeV protons from a tandem electrostatic accelerator. The beam current was 300-500 nA. During the irradiation, the target was cooled by liquid nitrogen to avoid the evaporation of volatile Cl compounds. The measured spectra for the NaCl standard samples clearly showed the Cl-Kβ series composed of the Kβ₁ and the satellite Kβ_x, Kβ₅ lines. From the measured X-ray yields, it was found that the chemical speciation of samples with Cl concentrations as low as ≈1% is possible by this method. The Cl-Kβ series were also successfully observed in the case of APM samples with particle sizes of 11.0-2.1 μm. The spectra shapes of the NaCl standard samples and an APM sample were slightly different from each other, because of some possible mixing of non-sea salt component in the APM sample.     

人参总皂苷对K562细胞的增殖抑制及诱导分化作用

目的:研究人参总皂苷TSPG对人慢性粒细胞白血病细胞株(K562细胞)增殖及分化的影响,探讨TSPG抗肿瘤作用.方法:取对数生长期K562细胞,分为阴性对照组、不同浓度TSPG组及阳性对照组进行体外培养,以噻唑蓝(MTT)比色法、台盼蓝活细胞计数法观察TSPG对K562细胞增殖的影响;用联苯胺染色及血红蛋白测定检测其诱...     

基于64K通道的继电保护缺陷分析与改进

针对2起RCS-931型继电保护64K通道的典型故障现象,进行了详细的分析和研究。分析了电流差动保护装置、PCM和光端机通信设备之间的2M、64K通道配合关系,并结合纵联电流差动保护工作原理,在现场通道试验基础上,阐明了通道故障产生的原因,64K保护用通道存在的缺陷,提出了行之有效解决方案和整改措施,为使用64K通道的...     

水热法制备K0.5Bi0.5TiO3陶瓷粉体及其介电性能研究

采用水热法合成了K0.5Bi0.5TiO3(KBT)无铅压电陶瓷粉体.运用X线衍射(XRD)分析了KOH浓度及反应时间对产物物相的影响;利用扫描电镜(SEM)和透射电镜(TEM)观察研究了粉体的形貌.结果表明,增大碱浓度(4～12 mol/L)和延长反应时间都有利于KBT纳米粉体的合成.在220℃,KOH的起始浓度12 mol/L水热合成48 h的纯KBT相呈立方形结构,晶型规整,晶粒尺寸约为100nm.由水热法制备的粉体在1060℃烧结,获得介电损耗为0.05的致密压电陶瓷材料.     

Ad-hoc网络的大步进节点发现算法

主要研究采用了定向天线的Ad-hoc网络中的节点发现策略,针对Ad-hoc网络中邻节点发现的阶段中,使用随机扫描算法带来的性能缺陷,提出了一种基于TDMA MAC协议的大步进节点发现扫描算法。该算法通过预先划分场景的区域,安排不同区域内的节点在不同扫描周期内扫描的顺序和方式,从而达到了加快邻节点发现的速度,减少建网时间,提高网络的性能。并通过理论推导、OPNET仿真和数据结果分析比较,验证了算法的性能。     

一种基于Tracker端偏向邻居选择的距离感知BitTorrent系统

To address cross-ISP traffic problem caused by BitTorrent, we present our design and evaluation of a proximity-aware BitTorrent system. In our approach, clients generate global proximityaware information by using landmark clustering; the tracker uses this proximity to maintain all peers in an orderly way and hands back a biased subset consisting of the peers who are physically closest to the requestor. Our approach requires no co-operation between P2P users and their Internet infra structures, such as ISPs or CDNs, no constantly path monitoring or probing their neighbors. The simulation results show that our approach can not only reduce unnecessary cross- ISP traffic, but also allow downloadsing fast.